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As for why Prime Catcher is so prized that it can end up in the top ten valuable cards list, its mainly down to the cards effect

BT15-049 SR Digimon Lv [Counter] Blast Digivolve (One of your Digimon may digivolve into this card without paying the cost.) [On Play] [When Digivolving] 1 of your Digimon gets +3000 DP until the end of your opponent's turn

The four decks are Gravestorm, Spirits & Arcane, Energy, and Stompy, each one using mechanics and themes the MTG Neural Net team felt were underused in regular Magic: The Gathering and could create cards that were wild and wacky

this card's ATK becomes double its original ATK until the end of your opponent's turn