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If the ability doesnt require tapping or untapping (like if theres just a mana cost), summoning sickness wont affect it

The first turn you play it, unless you are in dire need of cards, you should probably use its +1 ability to bring its loyalty up to 4

I would try and get Victini into the active Pokemon spot to start the game, then attach one energy card to it and use Turbo Energize to setup my benched Pokemon, because Victini EX has 110 hp, it should be able to endure your opponent's basic Pokemon's attacks for quite a few turns

All That Glitters All That Glitters differentiates itself from Ancestral Mask and Ethereal Armor by counting two types of permanents